you should probably consider the reference point of the track.
If you want your vocals to stand out, build your mix around the vocals.
The effects and what not come after considering the foundation of your mix with in basic aspects such as volume faders, panning, and frequency control.
The rest adds flavor, and will eventually be considered in the mix, but shouldn't necessarily be the building blocks of your music.
That being said, once you've laid the foundation with just the basic components, add in other effects one at a time to determine if it's the right tool for the job.
I'd also look up what the strength of each individual plug in (or just a bucket of plug ins) you're considering using for the chain. A bit of research goes a long ways in understanding how to develop your mixing techniques and eventually your own sound. It'll also increase your analysis skills if you know what and how something does in a more specific nature,.